Chelsea striker Diego Costa is left out of Spain coach Vicente del Bosque's provisional 25-man squad for Euro 2016 on Tuesday.
A Barcelona side without the injured Lionel Messi head to face Sevilla at Estadio Ramon Sanchez Pizjuan on Saturday, desperate to move back to the summit of La Liga.
Barcelona start the defence of their La Liga title Athletic Bilbao while Real Madrid kick-off the new season against Sporting Gijon.
Chelsea have agreed a deal with Barcelona to sign winger Pedro for a fee of £21m.
Athletic Bilbao win the Spanish Supercopa after beating Barcelona by an aggregate score of 5-1.
